Product ID:CALCO UNLEADED GASOLINE
MSDS Date:01/23/1992
FSC:9130
NIIN:01-282-2844
MSDS Number: BPMMH

CHEVRON ENVIRONMENTAL HEALTH CENTER INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804
US

Emergency Phone: 800-457-2022

Info Phone: 800-582-3835

Cage: 0AHD1

CHEVRON ENVIRONMENTAL HEALTH CENTER INC

4054 RICHMOND, CA 94804 US

Telephone: 800-582-3835

Cage: 0AHD1

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <4.9%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <6.5%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <9.7%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <3%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: <1.4%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

**CAN CONTAIN** METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15.0%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

**OR CAN CONTAIN** ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: <10.0%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9293

THE PREVIOUS 10 INGREDIENTS COMBINE TO FORM

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

LD50 LC50 Mixture:LD50 (ORAL RAT) IS >5 ML/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: PROLONGED OR FREQUENTLY
REPEATED CONTACT MAY CAUSE SKIN TO DEFAT AND IMPAIRMENT OF VISION.
INHALATION MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS, PULMONARY
EDEMA AND BRONCHITIS. CENTRAL NERVOUS S YSTEM EFFECTS, LUNG DAMAGE
IF SWALLOWEDOR ASPIRATED. CHRONIC: LIVER, KIDNEY AND BRAIN DAMAGE.
Explanation of Carcinogenicity:COMPONENTS OF GASOLINE ARE LISTED BY ALL
THREE AGENCIES.
Effects of Overexposure:EYES: PAIN, TEARS, SWELLING, REDNESS, BLURRED
VISION. SKIN: DRYNESS AND CRACKING. INHALE: HEADACHE, DIZZINESS,
LOSS OF APPETITE AND LOSS OF CORDINATION. HIGH CONCENTRATIONS MAY
CAUSE LOSS OF CONSCIOUS NESS, COMA AND DEATH. INGESTION MAY CAUSE
THE SAME SYMPTOMS AS INHALING ALONG WITH LUNG DAMAGE AND DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYE-FLUSH IMMEDIATELY WITH FRESH WATER FOR AT LEAST 15 MIN.
IF IRRITATION PERSISTS, SEE A DOCTOR. SKIN-NO FIRST AID REQUIRED.
HOWEVER, WASH SKIN THOROUGHLY WITH SOAP & WATER. INHALATION-IF
SYMPTOMS OC CUR, MOVE THE PERSON TO FRESH AIR. INGESTION-GIVE WATER
OR MILK TO DRINK & CALL FOR MEDICAL ADVICE. DO NOT MAKE PERSON
VOMIT UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. TAKE PERSON TO
HOSPITAL.

Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Autoignition Temp:Autoignition Temp Text:UNKNON
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:FIRE FIGHTING FOAM: ALCOHOL RESISTANT TYPE (AR),
AFFF, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING GASOLINE FIRES. THIS
PRODUCT PRESENTS AN EXTREME FIRE HAZARD.
Unusual Fire/Explosion Hazard:LIQUID VERY QUICKLY EVAPORATES, EVEN AT
LOW TEMPERATURES, AND FORMS VAPOR WHICH CAN CATCH FIRE AND BURN
WITH EXPLOSIVE VIOLENCE. EXTINGUISH ALL IGNITION SOURCES

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION IN VICINITY
OF SPILL OR RELEASED VAPOR. CLEAN UP SPILLS IMMEDIATELY. THIS
MATERIAL IS CONSIDERED TO BE A WATER POLLUTANT & RELEASE SHOULD BE
PREVENTED FROM CONTAMINAT ING SOIL, WATER & ENTERING DRAINAGE &
SEWER SYSTEM
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:NEVER SIPHON GASOLINE BY MOUTH. READ AND OBSERVE ALL
PRECAUTIONS ON PRODUCT LABEL. USE ONLY AS A MOTOR FUEL. DO NOT USE
FOR CLEANING, PRESSURE APPLIANCE FUEL, OR ANY OTHER SUCH USE.

Respiratory Protection:NO SPECIAL RESPIRATORY PROTECTION IS NORMALLY
REQUIRED. HOWEVER, IF OPERATING CONDITIONS CREATE AIRBORNE
CONCENTRATIONS WHICH EXCEED THE EXPOSURE STANDARDS, THE USE OF AN
APPROVED RESPIRATOR IS REQUIR ED.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED ARES.
Protective Gloves:NOT USUALLY NECESSARY.
Eye Protection:CHEMICAL GOGGLES.
Other Protective Equipment:SKIN CONTACT SHOULD BE MINIMIZED BY WEARING
PROTECTIVE CLOTHING. EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.

HCC:F1
Boiling Pt:B.P. Text:25 - 225C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:5-15 PSI
Vapor Density:3-4 AIR=1
Spec Gravity:0.7-0.8
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:INSOLUBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID.
Percent Volatiles by Volume:99+%
Corrosion Rate:UNKNOWNN

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES,
PILOT LIGHTS, WELDING EQUIPMENT, ELECTRICAL MOTORS AND SWITCHES.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
& WATER VAPORS; INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE.

Waste Disposal Methods:CLEAN UP SPILLS USING APPROPIATE TECHNIQUES SUCH
AS SORBENT MATERIALS/PUMPING. WHERE FEASIBLE & APPRPIATE, REMOVE
CONTAMINATED SOIL. PLACE CONTAMINATED MATERIALS IN DISPOSABLE
CONTAINERS & DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.